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Novel insights into the mechanisms controlling the heterogeneous distribution of arsenic-rich groundwater in the Yangtze River Basin from evolutionary analysis of sedimentary environment and groundwater flow systems
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Created: | Oct 15, 2025 at 3:14 a.m. (UTC) | |
Last updated: | Oct 15, 2025 at 5:32 a.m. (UTC) | |
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Sharing Status: | Public |
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Abstract
In the alluvial-lacustrine Jianghan Plain (JHP), the distribution of widespread but heterogenous arsenic(As)-contamination of groundwater is determined by the evolution of the groundwater flow system (GFS) since the Last Glacial Maximum (LGM), under the influence of progressively changing climate. Whereas, as a critical driving factor for As enrichment, the evolution of GFS has been largely overlooked. Based on the systematical integration of basin sedimentology, paleohydrogeology, and modern hydrogeochemical environment, this study establish a macro-scale theoretical framework linking “sedimentary evolution–GFS driving–geochemical field formation” in the JHP. Sedimentary environment of the aquifer system shaped by paleo-climatic changes has significantly influenced both GFS evolution and As-rich groundwater enrichment since the LGM. Beyond the reductive dissolution of amorphous As-rich minerals under favorable sedimentary conditions, the spatio-temporal GFS evolution plays a crucial role in As heterogeneity. Deep incision of the ancient Yangtze River channel leads to the most potent GFSs driving during the LGM. Rapid burial and weathering As-rich minerals provide the ample provenance during the late deglaciation period (LDP). The formation of an overlying clay cover during the Holocene warm period (HWP) ensures a reducing environment for underlying aquifer. These factors collectively lay the foundation for As-rich groundwater formation. Additionally, the continuous convergence of As-rich groundwater towards the regional discharge are is driven by the multiple-hierarchical GFS pattern alongside a gradually sluggish flow and upward discharge under a sustained hydraulic gradient, which contributed to the stable occurrence of As.
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Funding Agencies
This resource was created using funding from the following sources:
Agency Name | Award Title | Award Number |
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National Natural Science Foundation of China (Grant Nos. 42302289 and 42307274) |
Contributors
People or Organizations that contributed technically, materially, financially, or provided general support for the creation of the resource's content but are not considered authors.
Name | Organization | Address | Phone | Author Identifiers |
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Shuaishen | China University of Geosciences Wuhan |
How to Cite
This resource is shared under the Creative Commons Attribution CC BY.
http://creativecommons.org/licenses/by/4.0/
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