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Novel insights into the mechanisms controlling the heterogeneous distribution of arsenic-rich groundwater in the Yangtze River Basin from evolutionary analysis of sedimentary environment and groundwater flow systems


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Created: Oct 15, 2025 at 3:14 a.m. (UTC)
Last updated: Oct 15, 2025 at 5:32 a.m. (UTC)
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Abstract

In the alluvial-lacustrine Jianghan Plain (JHP), the distribution of widespread but heterogenous arsenic(As)-contamination of groundwater is determined by the evolution of the groundwater flow system (GFS) since the Last Glacial Maximum (LGM), under the influence of progressively changing climate. Whereas, as a critical driving factor for As enrichment, the evolution of GFS has been largely overlooked. Based on the systematical integration of basin sedimentology, paleohydrogeology, and modern hydrogeochemical environment, this study establish a macro-scale theoretical framework linking “sedimentary evolution–GFS driving–geochemical field formation” in the JHP. Sedimentary environment of the aquifer system shaped by paleo-climatic changes has significantly influenced both GFS evolution and As-rich groundwater enrichment since the LGM. Beyond the reductive dissolution of amorphous As-rich minerals under favorable sedimentary conditions, the spatio-temporal GFS evolution plays a crucial role in As heterogeneity. Deep incision of the ancient Yangtze River channel leads to the most potent GFSs driving during the LGM. Rapid burial and weathering As-rich minerals provide the ample provenance during the late deglaciation period (LDP). The formation of an overlying clay cover during the Holocene warm period (HWP) ensures a reducing environment for underlying aquifer. These factors collectively lay the foundation for As-rich groundwater formation. Additionally, the continuous convergence of As-rich groundwater towards the regional discharge are is driven by the multiple-hierarchical GFS pattern alongside a gradually sluggish flow and upward discharge under a sustained hydraulic gradient, which contributed to the stable occurrence of As.

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Funding Agencies

This resource was created using funding from the following sources:
Agency Name Award Title Award Number
National Natural Science Foundation of China (Grant Nos. 42302289 and 42307274)

Contributors

People or Organizations that contributed technically, materially, financially, or provided general support for the creation of the resource's content but are not considered authors.

Name Organization Address Phone Author Identifiers
Shuaishen China University of Geosciences Wuhan

How to Cite

Zhang, J., ShuaiShen (2025). Novel insights into the mechanisms controlling the heterogeneous distribution of arsenic-rich groundwater in the Yangtze River Basin from evolutionary analysis of sedimentary environment and groundwater flow systems, HydroShare, http://www.hydroshare.org/resource/31cd647f60df4dbd987d6a8c6e29b4e8

This resource is shared under the Creative Commons Attribution CC BY.

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