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Milford Neck - Redox Potential - Mar 2022-Jul 2024


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Created: Oct 20, 2022 at 6:04 p.m.
Last updated: Feb 06, 2025 at 9:46 p.m.
Published date: Feb 06, 2025 at 9:46 p.m.
DOI: 10.4211/hs.a67d5e40ec0043b79cbc3e1fb7034578
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Sharing Status: Published
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Abstract

This dataset includes redox potential (mV) at 6 different depths from 4 redox probes each at the Delaware Forested site (Milford Neck) for the CZNet Coastal Cluster. Redox potential was measured continuously in the field at 15-minute intervals with SWAP Instrument ORP-120-B redox probes installed into the ground. The probes each have 6 platinum electrode sensors that measure soil redox potential at 5 cm, 15 cm, 25 cm, 35 cm, 45 cm, and 120 cm from the ground surface. Each probe was connected to a Campbell CR1000X datalogger with a SWAP Instrument REF-12-0-A Ag/AgCl reference electrode. The reference electrode was installed below the ground surface at a depth that was always in contact with groundwater. The reference probes were installed into capped PVC surrounded by a 3 M KCl gel with holes drilled at the bottom of the PVC for contact with the groundwater. Redox potential values were corrected to the standard hydrogen electrode value by adding +200 mV to the measured potentials. Due to regular replacement of external data logger batteries and data downloads, there may be gaps in the data.

Subject Keywords

Coverage

Spatial

Coordinate System/Geographic Projection:
WGS 84 EPSG:4326
Coordinate Units:
Decimal degrees
Place/Area Name:
Milford Neck
North Latitude
38.9689°
East Longitude
-75.3703°
South Latitude
38.9668°
West Longitude
-75.3726°

Temporal

Start Date:
End Date:

Content

ReadMe.md

OVERVIEW

CZNet Cluster: Coastal

Contact: cznetcoastal@udel.edu

File description(s):

MilfordNeck_RX_220318-240709.csv - Redox potential (RX) at 6 depths below ground surface at each redox probe. Each column header is the name of a transect (site id) plus the variable (RX) plus the sensor depth (5, 15, 25, 35, 45, 120) in centimeters. Index column is the date and time of measurement (YYYY-MM-DD HH:MM:SS) in Eastern Standard Time. File name includes the date range (start date-end date as YYMMDD) of the dataset in Eastern Standard Time.

MN_RXsites.csv - Monitoring location names (site ids), depth intervals, location coordinates, and general description.

Keywords: Delaware; Milford Neck; Critical Zone; CZNet; CCZN; Soil; Redox Potential; Soil; Oxidation; Reduction; Biogeochemistry; Hydrology

TEMPORAL

Date start (YYYY-MM-DD): 2022-03-18

Date end (YYYY-MM-DD): 2024-07-09

SITE INFORMATION

Location: Milford Neck

Site description: Delaware Forested site

Installation date (YYYY-MM-DD): 2022-03-18

Site type: Soil

VARIABLE INFORMATION

Variable type: Chemistry

Variables: Redox Potential

Variables ODM2: reductionPotential

Variable abbreviations: Redox Potential - RX

No data value: NAN

Data flag: 999

Data flag meaning: Sensor malfunctioned at the time

TIME SERIES RESULTS INFORMATION

Units type: Redox Potential

Units name: millivolts

Units abbreviation: millivolts - mV

Status: Ongoing

Sample medium: Soil

Aggregation statistic: Continuous

UTC Offset Information: 5 hours (05:00:00)

METHOD INFORMATION

Method name: Redox Probe, SWAP Instruments ORP-120-B, Campbell Datalogger CR1000X

Method type: Instrument deployment

Method description: The redox probe was set to record continuously at 15-minute intervals on the CR1000X. Data were periodically downloaded from the Datalogger by stopping the Datalogger, downloading, replacing the battery, then restarting the deployment. There may be gaps in the data that occurred during this downloading period.

Method reference: Guimond, J. A., Seyfferth, A. L., Moffett, K. B., and Michael, H. A. (2020). A physical-biogeochemical mechanism for positive feedback between marsh crabs and carbon efflux. Environmental Research Letters, 15(3), 34024. https://doi.org/10.1088/1748-9326/ab60e2

Vepraskas, M. J., and J. L. Cox. (2002). "Redox potential measurements." NC State University, December 2002. https://files.knowyourh2o.com/pdfs/RedoxWriteup.pdf

Smit, Sander. (2022). Redox: redoxpotential probes. Paleo Terra. https://paleoterra.nl/index.html.

Processing information: Redox potential was processed by adding +200mV to the output from the datalogger.

Data validation and quality assurance: The probes cannot hold a calibration so the accuracy was checked with a calibration solution before deployment. The pre-installation check was performed using Hach Company +200mV ORP solution. The probes were submerged in this solution with a reference electrode to ensure that the sensors were reading potential correctly. The reference probe KCl solution is refilled when low and reference probes are checked during data downloads using an additional reference electrode connected to the datalogger as a sensor.

Additional Metadata

Name Value
Units Redox Potential - millivolts (mV)
Method Data collected using a SWAP Instrument ORP-120-B redox probe
Frequency 15-minute intervals
TimeStamp Times in this dataset are in Eastern Standard Time (EST); YYYY-MM-DD HH:MM:SS; UTC Offset - 5 hours
Variables Redox Potential
Dataset Type Multi-time series
Sample Medium Soil
Processing Level Millivolt values have had +200mV added to them to adjust for the estimated value had a standard hydrogen electrode been used and based on the reference electrode deployed (Ag/AgCl in saturated KCl solution).

Related Resources

This resource belongs to the following collections:
Title Owners Sharing Status My Permission
CCZN Milford Neck Data Rachel McQuiggan · Dannielle Pratt  Discoverable &  Shareable Open Access

Credits

Funding Agencies

This resource was created using funding from the following sources:
Agency Name Award Title Award Number
NSF Collaborative Research: Network Cluster: The Coastal Critical Zone: Processes that transform landscapes and fluxes between land and sea 2012484

Contributors

People or Organizations that contributed technically, materially, financially, or provided general support for the creation of the resource's content but are not considered authors.

Name Organization Address Phone Author Identifiers
Rachel McQuiggan University of Delaware;Delaware Geological Survey Delaware, US

How to Cite

Pratt, D., H. Michael, A. Sprague-Getsy, J. A. Guimond, E. S. Bacmeister (2025). Milford Neck - Redox Potential - Mar 2022-Jul 2024, HydroShare, https://doi.org/10.4211/hs.a67d5e40ec0043b79cbc3e1fb7034578

This resource is shared under the Creative Commons Attribution CC BY.

http://creativecommons.org/licenses/by/4.0/
CC-BY

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